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Question

Chemistry Question on coordination compounds

Identify correct statements from below:
A. The chromate ion is square planar.
B. Dichromates are generally prepared from chromates.
C. The green manganate ion is diamagnetic.
D. Dark green coloured K2MnO4K_2​MnO_4​ disproportionates in a neutral or acidic medium to give permanganate.
E. With increasing oxidation number of transition metal, ionic character of the oxides decreases.
Choose the correct answer from the options given below:

A

B, C, D only

B

A, D, E only

C

A, B, C only

D

B, D, E only

Answer

B, D, E only

Explanation

Solution

A. CrO42\text{CrO}_4^{2-} is tetrahedral.

B. 2Na2CrO4+2H+Na2Cr2O7+2Na++H2O2\text{Na}_2\text{CrO}_4 + 2\text{H}^+ \rightarrow \text{Na}_2\text{Cr}_2\text{O}_7 + 2\text{Na}^+ + \text{H}_2\text{O}

C. As per NCERT, green manganate is paramagnetic with 1 unpaired electron.

D. Statement is correct.

E. Statement is correct.