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Chemistry Question on Acids and Bases

Identify Bronsted-Lowry acids in the reaction given. [Al(H2O)2]3+(A)+HCO3(B)[Al(H2O)5(OH)]2+(C)\underset{(A)}{\mathop{{{[Al{{({{H}_{2}}O)}_{2}}]}^{3+}}}}\,+\underset{(B)}{\mathop{HCO_{3}^{-}}}\,\underset{(C)}{\mathop{{{[Al{{({{H}_{2}}O)}_{5}}(O{{H}^{-}})]}^{2+}}}}\, +H2CO3(D)\underset{(D)}{\mathop{+{{H}_{2}}C{{O}_{3}}}}\, The correct answer is

A

,

B

(B,)

C

,

D

,

Answer

,

Explanation

Solution

According to Bronsted-Lowry, acids are the substance which can donate a proton while bases are the substance which can accept a proton. A base after gaining a proton (H+)({{H}^{+}}) gives conjugated acid. [Al(H2O)6]3+acid+HCO3(B) base\underset{acid}{\mathop{{{[Al{{({{H}_{2}}O)}_{6}}]}^{3+}}}}\,+\underset{\begin{smallmatrix} (B) \\\ base \end{smallmatrix}}{\mathop{HCO_{3}^{-}}}\,\rightleftharpoons [Al(H2O)5(OH)]2+C conjugatebase+H2CO3(D) conjugateacid\underset{\begin{smallmatrix} \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C \\\ conjugate\,base \end{smallmatrix}}{\mathop{{{[Al{{({{H}_{2}}O)}_{5}}(O{{H}^{-}})]}^{2+}}}}\,+\underset{\begin{smallmatrix} \,\,\,\,\,\,\,\,\,\,\,\,\,(D) \\\ conjugate\,acid \end{smallmatrix}}{\mathop{{{H}_{2}}C{{O}_{3}}}}\, Hence, in the above reaction A and D are the acids.