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Question: Ice at 0<sup>0</sup>C is added to 200gm of water initially at 70<sup>0</sup>C in a vacuum flask. Whe...

Ice at 00C is added to 200gm of water initially at 700C in a vacuum flask. When 50 gm of ice has been added and has all melted, the temperature of flask and contents is 400C, When a further 80 gm of ice is added and has all melted, the temperature of whole becomes 100C. Neglecting heat lost to surroundings the latent heat of fusion of ice is :

A

80 cal/gm

B

90 cal/gm

C

70 cal/gm

D

540 cal/gm

Answer

90 cal/gm

Explanation

Solution

Accoding to principle of calorimetry,

MLF + Ms DT = (msDT)water + (msDT)flask

50Lf + 50 × I × (40 – 0)

= 200 × 1 × (70–40) + W (70 – 40)

or 50Lf + 200 = (200 + W) 30

or 5Lf = 400 + 3W ................(i)

Now the system contains(200 + 50) gm of water at 400C, so when further 80 gm of ice is added.

80Lf + 80 × 1 × (10 – 0)

= 250 × 1 × (40 – 10) + W (40 – 10)

or 80Lf + 800 = (250 + W)30

or 80Lf = 670 + 3W ...............(ii)

Solving equation (i) and (ii),

Lf = 90 cal/gm and W = 503\frac{50}{3}gm