Question
Question: Ice at 0<sup>0</sup>C is added to 200gm of water initially at 70<sup>0</sup>C in a vacuum flask. Whe...
Ice at 00C is added to 200gm of water initially at 700C in a vacuum flask. When 50 gm of ice has been added and has all melted, the temperature of flask and contents is 400C, When a further 80 gm of ice is added and has all melted, the temperature of whole becomes 100C. Neglecting heat lost to surroundings the latent heat of fusion of ice is :
80 cal/gm
90 cal/gm
70 cal/gm
540 cal/gm
90 cal/gm
Solution
Accoding to principle of calorimetry,
MLF + Ms DT = (msDT)water + (msDT)flask
50Lf + 50 × I × (40 – 0)
= 200 × 1 × (70–40) + W (70 – 40)
or 50Lf + 200 = (200 + W) 30
or 5Lf = 400 + 3W ................(i)
Now the system contains(200 + 50) gm of water at 400C, so when further 80 gm of ice is added.
80Lf + 80 × 1 × (10 – 0)
= 250 × 1 × (40 – 10) + W (40 – 10)
or 80Lf + 800 = (250 + W)30
or 80Lf = 670 + 3W ...............(ii)
Solving equation (i) and (ii),
Lf = 90 cal/gm and W = 350gm