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Question

Chemistry Question on Equilibrium

Hybridization of Fe in K3[Fe(CN)6] is:

A

(A) sp3

B

(B) d2sp3

C

(C) sp3 d2

D

(D) dsp3

Answer

(B) d2sp3

Explanation

Solution

Explanation:
Hybridization of Fe in K3[Fe(CN)6] is d2sp3.In the given complex of Fe3+, as the co-ordination number is ' 6 ', there are two possibilities. It can be d2sp3 or sp3d2. But the ligand attached with central metal ion, Fe3+, is strong field ligand so it willpromate inner orbital complex, d2sp3.Hence, the correct option is (B).