Question
Chemistry Question on Amines
The correct decreasing order of pKb is
A
I > II > III > IV
B
III > IV > II > I
C
II > III > IV > I
D
IV > II > I > III
Answer
IV > II > I > III
Explanation
Solution
Substituent with strong +R effect, +I effect and weaker −I effect increases the basicity. Hence PKb decreases. Also, alkylamines are stronger bases than arylamines. So, the order is (d).