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Question

Chemistry Question on Amines


The correct decreasing order of pKbpK_b is

A

I > II > III > IV

B

III > IV > II > I

C

II > III > IV > I

D

IV > II > I > III

Answer

IV > II > I > III

Explanation

Solution

Substituent with strong ++R effect, +I+I effect and weaker I-I effect increases the basicity. Hence PKbPK_{b} decreases. Also, alkylamines are stronger bases than arylamines. So, the order is (d).