Question
Question: How would you name the following compound? .
RULE: 5
When the compound has more than one group the groups are named alphabetically. The prefixes used while naming the group are iso, for example isobutyl.
RULE: 6
If the parent chain has the same number of carbon, then the chain which has more side chains, lowest number of substituents, or the chain that has lowest branches are preferred.
RULE: 7
A ring hydrocarbon is denoted with cyclo which is written before the name of the compound.
RULE: 8
In case of unsaturated hydrocarbons, like alkene or alkynes the base name should end with –ene or –ane. Triple bonds are also named in this way, they have –yne added at the end of base name.
RULE: 9
The parent chain with multiple bonds is numbered in a way that the multiple bond gets the first number. Double or triple bonds have priority over other substituent groups. Always remember if there is a double and single bond present the lowest numbering is given to a double bond.
Now let’s name the compound given above, look for the parent chain. It has one carbon so for one carbon we say ‘meth’. It also has a double bond and a substituent as ′OH′ . So the compound would be called ‘methanol’. We use ′Ol′ as a suffix for alcohol.
Additional Information:
The base name refers to the number in the parent chain. The suffix decides the functional group of the compound. As mentioned above other groups are known as substituents.
NUMBER OF CARBONS | NAME |
---|---|
1 | Meth |
2 | Eth |
3 | Prop |
4 | But |
5 | Pent |
6 | Hex |
7 | Hep |
8 | Oct |
9 | Non |
10 | Dec |
Note:
In chemistry, nomenclature is assigned by the international union of pure and applied chemistry (IUPAC). Which is published in the blue book of organic chemistry. For simple molecules we use more common names rather than the name provided by the IUPAC. We use certain prefixes, suffixes and infixes to describe the name of the compound. Let’s revisit all the rules in one or two lines. First we identify then we give highest precedence, then identify the functional group, put the prefix and suffix.