Question
Question: How will you convert acetylene into but-1yne?...
How will you convert acetylene into but-1yne?
Solution
This reaction will occur in multiple steps. One might require to add a base or an acid to lead towards the product. A basic alkyl halide is used to form the final product, which is a step in between the initial and the last one.
Complete answer:
The acetylene formula is: H−C≡C−H
The formula for but-1-yne:H2C=CH−CH2−CH3
The H of acetylene is acidic, because when H+ proton loss, we get an anion.
In step one: the H+ proton loss, anion we get is HC≡C−
H−C≡C−H→HC≡C−
We are aware of triple bond; the s character is 50%. This means it is more electronegative, and it will attract the less electron rich atoms to stabilise the atom.
In step two: Now if we react the anion with NaNH2 a base, the protonic H+ will loose and the rest highly negative anion will reactNa+ and form with amino group forms ammonia.
HC≡C−NaNH2HC≡C−Na++NH3
In step third: we react the above formed with C2H5Br we get,