Solveeit Logo

Question

Question: How many \(s{p^3}\) hybridised carbon atoms are in Acetophenone?...

How many sp3s{p^3} hybridised carbon atoms are in Acetophenone?

Explanation

Solution

Acetophenone is an organic compound. Acetophenone is the simplest aromatic ketone with the chemical formula C6H5C(O)CH3{C_6}{H_5}C\left( O \right)C{H_3}. sp3s{p^3} hybridisation is formed by the intermixing of one ss orbital and three pp orbitals.

Complete step by step solution
The concept of hybridisation is given by Pauling. According to Pauling the atomic orbitals having slightly different energy and shape are intermixed to form hybrid orbital. These hybrid orbitals are involved in bond formation and these hybrid orbitals are equivalent in energy.

spsp hybridisation-In this hybridisation one ss and one pp orbitals intermixes. Due to this intermixing two equivalent spsp hybrid orbitals are formed. Similarly, in sp2s{p^2} hybridisation one ss and two pp orbitals intermix. Due to this intermixing three equivalent sp2s{p^2} hybrid orbitals are formed .Similarly in case of sp3s{p^3} hybridisation one ss and one pp orbitals intermixes. Due to this intermixing four equivalent sp3s{p^3} hybrid orbitals are formed.
Acetophenone has the chemical formula C6H5C(O)CH3{C_6}{H_5}C\left( O \right)C{H_3}.

Above is the figure of Acetophenone. It has eight carbon atoms, in which six carbon atoms involved in the formation of benzene. Then one carbon is involved in the ketone functional group and the other carbon atom is involved in methyl.

First take a look at all benzene involved carbons i.e. the carbon numbers 3,4,5,6,7,83,4,5,6,7,8 .All these six carbons have 33 sigma bonds and 11 pi bonds connected to carbon atoms. So, the hybridisation of all six carbons which is involved in benzene is sp2s{p^2} hybridised. Now take a look at carbonyl carbon i.e. carbon number 22 which has 33 sigma bonds and 11 pi bonds connected to oxygen.

Now take a look at carbon number 11,which is connected to one carbonyl carbon and three hydrogen atoms. So, the hybridisation of carbon 11 becomes sp3s{p^3} hybridised.
Hence only one carbon i.e. carbon 11 becomes sp3s{p^3} hybridised.

Note:
Thus in case of spsp hybridisation one ss and one pp orbital involved so spsp hybridisation has 50%50\% s and 50\% $$$p$$ character. Similarly in s{p^2}hybridisationonehybridisation one sand two $$p$$ orbitals are involved sos{p^2}hybridisationhashybridisation has 33.33% sandand66.66% p$$ character. While $s{p^3}$ in hybridisation one $s$ and three $$p$$ orbitals are involved so $s{p^3}$ hybridisation has $25\% $ $s$ and $75\% $ $75\% p$$ character.