Solveeit Logo

Question

Question: How is entropy related to the spontaneity of a reaction?...

How is entropy related to the spontaneity of a reaction?

Explanation

Solution

1)The second law of thermodynamics says that the entropy of the universe consistently increments for an spontaneous process: ΔSuniverse=ΔSsystem+ΔSsurrounding>0\Delta {S_{universe}} = \Delta {S_{system}} + \Delta {S_{surrounding}} > 0
2)A consistent temperature and pressure, the adjustment in Gibbs free energy is defined as
ΔG=ΔHTΔS\Delta G = \Delta H - T\Delta S
3)The spontaneity of a process can rely upon the temperature

Complete step by step answer:
Entropy (S) is a proportion of the disorder in a system.
In a closed system, entropy consistently increases after some time. In an open system, energy can be added to a system to cause a lessening in entropy, however this isn't really a spontaneous reaction.
In the event that entropy (disorder) increases, and the reaction enthalpy is exothermic (ΔH<0\Delta H < 0) or
pitifully endothermic (ΔH>0\Delta H > 0 and small), the reaction is for the most part spontaneous.
The Gibbs free energy condition is:
ΔG=ΔHTΔS\Delta G = \Delta H - T\Delta S
A reaction will be spontaneous if the adjustment in G, ΔG\Delta G , is negative.
For the result of temperature times ΔS\Delta S , whereΔS\Delta S is the change in entropy, if the change in entropy is positive (disorder increases), then TδST\delta S, when subtracted, gets negative.
Since the cosmos (discernible universe) is basically a closed system, entropy will keep on expanding until the universe basically stops to exist.

Note: When ΔG<0\Delta G < 0 , the process is exergonic and will continue spontaneously the forward direction to form more products.
When ΔG>0\Delta G > 0 , the process is endergonic and not spontaneous in the forward direction. All things being equal, it will continue spontaneously in the opposite direction to make more beginning materials.
When ΔG=0\Delta G = 0 , the system is in equilibrium and the concentrations of the products and reactants will stay consistent.