Question
Question: How is acetic acid prepared from acetylene?...
How is acetic acid prepared from acetylene?
Solution
The acetic acid is a carboxylic acid, having two carbons, one is of carboxylic acid and one is of methyl group and having formula of acetic acid as CH3COOH . Acetylene is an alkyne having two carbons and a triple bond and having formula of acetylene as C2H2 .
Complete step by step answer:
Here, for these question, we have to convert acetylene into acetic acid:
We cannot directly change alkynes into carboxylic acid, for these we have to convert the alkyne into aldehyde first and then convert the aldehyde into the carboxylic acid by oxidation of aldehyde.
For this first of all, we have to convert the acetylene into acetaldehyde. Acetaldehyde is an aldehyde having two carbons, one of the carbon as aldehyde group as functional group and another as methyl group having formula CH3CHO .
The acetylene is converted into acetaldehyde by reacting the acetylene with 40%H2SO4 at 60∘C in the presence of 1%HgSO4 .
The reaction of conversion of acetylene into acetaldehyde is as follows:
C2H2+H2OH2SO4(dil.)HgSO4CH3CHO
Now, we have to convert acetaldehyde into acetic acid.
The acetaldehyde is oxidised in the presence of catalyst manganese acetate.
The reaction of conversion of acetaldehyde into acetic acid as follows:
CH3CHO+[O]CatalystΔCH3COOH
So, the complete conversion of the acetylene into acetic acid as follows:
C2H2+H2OH2SO4(dil.)HgSO4CH3CHO
CH3CHO+[O]CatalystΔCH3COOH
So, we can prepare the acetic acid from acetylene by the above conversions.
Note:
Acetic acid and acetylene are the common names of the CH3COOH and C2H2 . The IUPAC name of acetic acid is ethanoic acid and the IUPAC name of acetylene is ethyne. IUPAC naming is recommended by the International Union of Pure and Applied Chemistry.