Question
Question: How does \(Sn_1\) reactions differ from \(Sn_2\) reactions?...
How does Sn1 reactions differ from Sn2 reactions?
Solution
The Sn1 reaction and Sn2 reaction are the two types of nucleophilic substitution reaction where the suffix 1 and 2 denotes that the reaction is unimolecular reaction and bimolecular reaction.
Complete step by step answer:
The nucleophilic substitution reaction is a type of reaction where one nucleophile substitutes the other nucleophile. The nucleophilic substitution reaction is divided into Sn1 reaction and Sn2 reaction. The Sn1 reaction is known as nucleophilic substitution reaction 1 and Sn2 reaction is the nucleophilic substitution reaction 2.
In nucleophilic substitution reaction, the group that takes the electron pair and removes it from the carbon is known as the leaving group and the molecule on which the substitution takes place is known as substrate.
The difference between Sn1 reaction and Sn2 reactions is shown below.
Sn1reaction:
(1) Sn1 is a unimolecular reaction.
(2) In Sn1 reaction, two steps are involved
(3) In Sn1 reaction, the rate of reaction depends on the concentration of substrate.
(4) The Sn1 reaction follows the first order of kinetic mechanism.
(5) In Sn1 reaction, the leaving group leaves and substrate forms a carbocation intermediate.
Sn2 reaction:
(1) Sn2 is a bimolecular reaction.
(2) The Sn2 reaction is a single step reaction.
(3) The Sn2 reaction depends on the concentration of both the substrate and nucleophile.
(4) The Sn2 reaction follows the second order of kinetic mechanism.
(5) The Sn2 reaction takes place in a single transition state.
Note:
In the nucleophilic substitution reaction, the leaving group leaves the molecule as a neutral atom or an anion. The nucleophilic substitution reaction is the same as the displacement reaction.