Question
Question: How does \(s{{p}^{2}}\)hybridized carbon differ from \(s{{p}^{3}}\)?...
How does sp2hybridized carbon differ from sp3?
Solution
Hybridization is the process of intermixing of the orbitals of slightly different energies so as to redistribute their energies, resulting in the formation of new set of orbitals of equivalent energies and shape. sp2andsp3hybridization are types of hybridization.
Complete step-by-step answer: sp2hybridization is a form of orbital hybridization in which 1 s orbital overlaps with 2 p orbitals to form three new hybrid orbitals.
sp3hybridization is a form of orbital hybridization in which 1 s orbital overlaps with 3 p orbitals to form four new hybrid orbitals.
If carbon in a carbon compound undergo sp2hybridization then it is referred to as sp2hybridized carbon atom and if the same carbon undergoes sp3hybridization, then the carbon is called sp3hybridized carbon atom.
The differences between both the hybridized carbon atoms are mentioned below in tabular form.
FEATURE | sp2hybridized carbon | sp3hybridized carbon |
---|---|---|
Definition | A form of orbital hybridization in which one s-orbital of carbon overlaps with two p orbitals to form three new hybrid orbitals. | A form of orbital hybridization in which one s-orbital of carbon overlaps with three p orbitals to form four new hybrid orbitals. |
s- characteristic | In such carbon the s character is 33 | In such carbon the s character is 25 |
p- characteristic | In such hybridized carbon the p character is 66 | In such hybridized carbon the p character is 75 |
Geometry | It has trigonal planar geometry | It has Tertrahedral geometry |
Bond angle | 120∘ | 109.5∘ |
Unhybridized p orbital | One un-hybridized p orbital is present in such carbon | No un-hybridized p orbital is present in such carbon |
Examples | Carbon in ethene is sp2hybridized as shown below ![]() | Carbon in ethane is sp3hybridized as shown below. ![]() |
Note: It should be noted that for explaining the characteristic shapes of the polyatomic molecule, Pauling- a great chemist, scientist introduced the concept of hybridization of the atomic orbitals. Always, draw structures while mentioning the types of hybridization for better reference.