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Question

Chemistry Question on Alcohols, Phenols And Ethers

How are the following conversions carried out?

(i)Propene\rightarrowPropan-2-ol.

(ii)Benzyl chloride\rightarrowBenzyl alcohol.

(iii)Ethyl magnesium chloride\rightarrowPropan-1-ol.

(iv)Methyl magnesium bromide\rightarrow2-Methylpropan-2-ol.

Answer

(i)If propene is allowed to react with water in the presence of an acid as a catalyst,then propan-2-ol is obtained.

(ii)If benzyl chloride is treated with NaOH(followed by acidification)then benzyl alcohol is produced.

(iii)When ethyl magnesium chloride is treated with methanol, an adduct is produced which gives propan-1-ol on hydrolysis.

(iv)When methyl magnesium bromide is treated with propane, an adduct is the product that gives 2- methylpropane-2-ol on hydrolysis.