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Question

Chemistry Question on Amines

Hofmann degradation of benzamide gives aniline. Hofmann bromamide degradation reaction can be used for descending amine series.

A

If both assertion and reason are true and reason is the correct explanation of assertion

B

If both assertion and reason are true but reason is not the correct explanation of assertion

C

If assertion is true but reason is false

D

If both assertion and reason are false

Answer

If both assertion and reason are true and reason is the correct explanation of assertion

Explanation

Solution

Hoffmann Bromamide reaction is a method of preparing primary amines. Reagent: Amide reaction with bromine and NaOH. RCONH2+Br2+4NaOHRNH2+Na2CO3+2NaBr+2H2OR- \overset{\underset{||}{O}}{C}-NH _{2}+ Br _{2} +4 NaOH \rightarrow R - NH _{2}+ Na _{2} CO _{3}+2 NaBr +2 H _{2} O The amine formed has one carbor less than the parent amide.