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Question

Chemistry Question on d -and f -Block Elements

Highest oxidation state of manganese in fluorides is +4(MnF4)+4 (MnF_4) but highest oxidation state in oxides is +7(Mn2O7)+7 (Mn_2O_7) because

A

fluorine is more electronegative than oxygen

B

fluorine does not possess dd-orbitals

C

fluorine stabilises lower oxidation state

D

in covalent compounds, fluorine can form single bond only while oxygen forms double bond

Answer

in covalent compounds, fluorine can form single bond only while oxygen forms double bond

Explanation

Solution

Oxygen can form pπpπp\pi-p\pi bonding while fluorine can form only single bonds.