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Question

Chemistry Question on Chemical Reactions

Heating white phosphorus with conc. NaOHNaOH solution gives mainly:

A

Na3PNa_3P and H2OH_2O

B

H3POH_3PO and NaHNaH

C

P(OH)3P(OH)_3 and NaH2PO4NaH_2PO_4

D

PH3PH_3 and NaH2PO2NaH_2PO_2

Answer

PH3PH_3 and NaH2PO2NaH_2PO_2

Explanation

Solution

Heating white phosphorus with concentrated NaOHNaOH solution results to the following reaction :

P4(white)+NaOHPH3\+NaH2PO2\+H2OP_4(white) + NaOH → PH_3 \+ NaH_2PO_2 \+ H_2O

Hence, the correct option is (D): PH3PH_3 and NaH2PO2NaH_2PO_2