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Question: Heating of \[MgC{l_2}.6{H_2}O\] gives anhydrous \[MgC{l_2}\] . If true enters 1, else enter 0....

Heating of MgCl2.6H2OMgC{l_2}.6{H_2}O gives anhydrous MgCl2MgC{l_2} . If true enters 1, else enter 0.

Explanation

Solution

MgCl2.6H2OMgC{l_2}.6{H_2}Oon heating will give MgCl2MgC{l_2} and 6H2O6{H_2}O and it means that MgCl2MgC{l_2} is available in anhydrous form. MgCl2.6H2OMgC{l_2}.6{H_2}O removes water.

Complete step wise step answer:
MgCl2.6H2OMgC{l_2}.6{H_2}O undergoes partial hydrolysis on its own water molecules of crystallization when it is heated. MgCl2.6H2OMgC{l_2}.6{H_2}O upon heating gives MgCl2.2H2OMgC{l_2}.2{H_2}O and then Mg(OH)ClMg\left( {OH} \right)Cl or MgOCl + HClMgOCl{\text{ }} + {\text{ }}HCl which it is strongly heated gives MgO. When MgCl2MgC{l_2} is strongly heated, then it forms MgO.
On heating, MgCl2.6H2OMgC{l_2}.6{H_2}O readily loses 4 molecules of water of crystallization to form MgCl2MgC{l_2}. Upon heating, MgCl2.6H2OMgC{l_2}.6{H_2}O went upon the processes of dehydration and hydrolysis simultaneously accompanied by the release of HCl between 1500C{150^0}C and 500C500^\circ C. The remaining two molecules of water are not removed but react chemically with MgCl2MgC{l_2} to form MgO. The thermal decomposition mechanisms and the intermediate morphology of MgCl2.6H2OMgC{l_2}.6{H_2}O and MgCl2.H2OMgC{l_2}.{H_2}O were observed using integrated thermal analysis, X-ray diffraction, scanning electron microscope and chemical analysis.
This results showed that there was six steps in the thermal decomposition of MgCl2.6H2OMgC{l_2}.6{H_2}O: producing MgCl2.4H2OMgC{l_2}.4{H_2}O at 69C69^\circ C, MgCl2.2H2OMgC{l_2}.2{H_2}O at 129C129^\circ C, MgCl2.H2OMgC{l_2}.{H_2}O (1n2)\left( {1 \leqslant n \leqslant 2} \right) and Mg(OH)ClMg(OH)Cl at 167C167^\circ C ,
the conversion of MgCl2.H2OMgC{l_2}.{H_2}O (1n2)\left( {1 \leqslant n \leqslant 2} \right) to Mg(OH)Cl.3H2OMg(OH)Cl.3{H_2}O by continuous dehydration and hydrolysis at 203C203^\circ C, the dehydration of Mg(OH)Cl.3H2OMg(OH)Cl.3{H_2}O to Mg(OH)ClMg(OH)Cl at 235C235^\circ C , and hence the direct conversion of Mg(OH)ClMg(OH)Cl to the cylindrical particles of MgO at 415C415^\circ C.
So, It's true that MgCl2.6H2OMgC{l_2}.6{H_2}O on heating gives anhydrous MgCl2MgC{l_2} ,

so we enter 1.

Note: MgCl2.6H2OMgC{l_2}.6{H_2}O went through the processes of dehydration and hydrolysis simultaneously accompanied by the release of HCl between 1500C{150^0}C and 500C500^\circ C. At a temperature higher than 500C500^\circ C, Mg(OH)ClMg\left( {OH} \right)Cl gradually releases part of HCl.