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Question

Chemistry Question on Structure of atom

Heat treatment of muscular pain involves radiation of wavelength of about 900nm900\, nm. Which spectral line of H-atom is suitable for this purpose ? [RH=1×105  cm1,h=6.6×1034  Js,c=3×108  ms1][R_H = 1 \times 10^5 \; cm^{-1}, h = 6.6 \times 10^{-34} \; Js, c = 3 \times 10^8 \; ms^{-1}]

A

Paschen, 535\to 3

B

Paschen, 3\infty \to 3

C

Lyman, 1\infty \to 1

D

Balmer, 2\infty \to 2

Answer

Paschen, 3\infty \to 3

Explanation

Solution

We have,
1λ=RZ2(1nl21nf2)\frac{1}{\lambda}=R Z^{2}\left(\frac{1}{n_{l}{ }^{2}}-\frac{1}{n_{f}{ }^{2}}\right)
Here if nl=3n _{l}=3 and nf=n _{ f }=\infty
1λ=107×12(12312)=1079=900mm\frac{1}{\lambda}=10^{-7} \times 1^{2}\left(\frac{1^{2}}{3}-\frac{1}{\infty^{2}}\right)=\frac{10^{-7}}{9}=900\, mm