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Question

Chemistry Question on Thermodynamics

Heat of neutralization of any strong acid and strong base is always constant and ΔH=57.3kJ\Delta H= -57.3 \, kJ. This is because

A

both the acid and base undergo complete ionization

B

during neutralization salt and water are formed

C

1 mole of water is formed from \ceH+\ce{H^+} and \ceOH\ce{OH^-} ions

D

the reaction is exothermic

Answer

1 mole of water is formed from \ceH+\ce{H^+} and \ceOH\ce{OH^-} ions

Explanation

Solution

The enthalpy of neutralization of any strong acid with a strong base is always the same, i.e., 57.1 kJ. This is because the strong acids, strong bases and the salts they form, are all completely ionized in dilute aqueous solution.
Na+=OH+H++Cl>Na++Cl+H2O{ Na^+ = OH^- + H^+ + Cl^- -> Na^+ + Cl^- + H_2 O} or H(aq)++OH(aq)>H2O(l) { H^+_{(aq)} + OH^-_{(aq)} -> H_2O_{(l)} }
i.e.; 1 mole of water is formed from H+ {H^+} and OH {OH^-} ions.