Question
Question: Halides of \(III\)A group element predominantly acts as? A.Lewis base B.Lewis acid C.Arrheniu...
Halides of IIIA group element predominantly acts as?
A.Lewis base
B.Lewis acid
C.Arrhenius acid
D.Neutral halide
Solution
The halides of III are present in the p block, because the electrons are filled till the p orbit.
Complete answer:
Halides of IIIA group in a trivalent state only have 6electrons in their orbit. In order to complete their orbit they tend to receive electrons. This completes their octet state. Lewis bases tend to donate electrons since they are electron rich. They occupy higher orbit molecular states and hence have a tendency to donate. While Lewis acid has an orbit that is empty and can be filled. Hence they are called electron receiving groups. Since halide IIIA displays the same quality they act as Lewis base. Arrhenius acids tend to form salt and water in any reaction by giving H+ions . And since the halides are receiving electrons they are not neutral and hence cannot act as a neutral halide. Therefore they show the properties of Lewis acid.
Hence, option B Lewis acid
Note:
Along with onium ions H+ions can be considered as Lewis acid. Basically any electron deficient atom can act as a Lewis acid. Trigonal planar elements tend to accept electrons too making it act like Lewis acid.