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Question

Chemistry Question on Redox reactions

H2S {H_2S} is passed through an acidified solution of copper sulphate and a black precipitate of cupric sulphide is formed. This is due to

A

oxidation of \ceCu2+\ce{Cu^{2+}}

B

reduction of \ceCu2+\ce{Cu^{2+}}

C

double decomposition

D

reduction and oxidation

Answer

double decomposition

Explanation

Solution

{\overset{\text{ +2}}{ { Cu}}\,\overset{\text{ +6}}{ { S}}\,\overset{\text{ -2}}{ { O}}4+_4 + \overset{\text{ +1}}{ { H}}2_2 \, \overset{\text{ -2}}{ { S}}>->\overset{\text{ +2}}{ { Cu}}\,\overset{\text{ -2}}{ { S}}++\overset{\text{ +1}}{ { H}}2_2 \, \overset{\text{ +6}}{ { S}}\,\overset{\text{ -2}}{ { O}}_4 } Here O.N. of all the atoms remains unaltered, therefore, it is not a redox reaction but is a double decomposition reaction.