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Question

Question: Gold\[ - 198\] has a half-life of \[2.7{\text{ days}}\].How much of a \[96g\] sample of Gold\[ - 198...

Gold198 - 198 has a half-life of 2.7 days2.7{\text{ days}}.How much of a 96g96g sample of Gold198 - 198 will be after 8.18.1 days?

Explanation

Solution

Radioactive decay follows first order kinetics.
Use the concept of half-life of first order kinetics and the formula of half-life for first order kinetics is
t12=0.693λ{t_{\dfrac{1}{2}}} = \dfrac{{0.693}}{\lambda } Here λ\lambda is rate constant of gold
And use the equation of first order to find the remaining concentration after given time

Complete step-by-step answer:
Now it is given in the question that Gold198 - 198 has a half-life of2.7 days2.7{\text{ days}}.
That means the value oft12=2.7 days{t_{\dfrac{1}{2}}} = 2.7{\text{ days}}.
Now using the equation of half-life which is t12=0.693λ{t_{\dfrac{1}{2}}} = \dfrac{{0.693}}{\lambda } we will find the value of rate constantλ\lambda .
The value of λ\lambda will be λ=0.693t12\lambda = \dfrac{{0.693}}{{{t_{\dfrac{1}{2}}}}}
Putting the value of half time of gold we will get the rate constant which is
λ=0.6932.7\lambda = \dfrac{{0.693}}{{2.7}}
λ=0.256 days1\lambda = 0.256{\text{ day}}{{\text{s}}^{ - 1}}
Now the equation of first order kinetics is N=N0×eλtN = {N_0} \times {e^{ - \lambda t}}
Here, NN is the amount left after tt time
N0{N_0} Is the initial amount which is = 96g96g
λ\lambda Is the rate constant whose value we had founded earlier = 0.260.26
And the value of tt is given in question which is t=8.1 dayst = 8.1{\text{ days}}
Now putting all the values in the equation N=N0×eλtN = {N_0} \times {e^{ - \lambda t}} we will get
N=96×e0.256days1×8.1daysN = 96 \times {e^{ - 0.256day{s^{ - 1}} \times 8.1days}}
Now solving it we will get N=12gN = 12g

Thus the amount of Gold198 - 198 left after 8.1 days8.1{\text{ days}} is 12grams12grams

Note: The values unit should be the same at all the places and the thing which is to be noted that all the radioactive decays follow the first-order kinetics. Half-life, in radioactivity, the interval of time required for one-half of the atomic nuclei of a radioactive sample to decay (change spontaneously into other nuclear species by emitting particles and energy), or, equivalently, the time interval required for the number of disintegrations per second of radioactive material to decrease by one-half.