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Question

Question: Given \({E^{o}}_{Ag^{+}/Ag} = + 0.80V;{E^{o}}_{Cu^{2 +}/Cu} = + 0.34V;\) \({E^{o}}_{Fe^{3 +}Fe^{2 +...

Given EoAg+/Ag=+0.80V;EoCu2+/Cu=+0.34V;{E^{o}}_{Ag^{+}/Ag} = + 0.80V;{E^{o}}_{Cu^{2 +}/Cu} = + 0.34V;

EoFe3+Fe2+=+0.76V;EoCe4+/Ce3+=+1.60V{E^{o}}_{Fe^{3 +}Fe^{2 +}} = + 0.76V;{E^{o}}_{Ce^{4 +}/Ce^{3 +}} = + 1.60V

Which of the following statements is not correct?

A

Fe3+Fe^{3 +} does not oxidize Ce3+Ce^{3 +}

B

Cu reduces Ag+Ag^{+}to Ag.

C

Ag will reduce Cu2+Cu^{2 +}to Cu.

D

Fe3+Fe^{3 +}reduces Cu2+Cu^{2 +}to Cu.

Answer

Ag will reduce Cu2+Cu^{2 +}to Cu.

Explanation

Solution

: Since Ag has higher reduction potential than Cu, Ag will not reduce Cu2+Cu^{2 +}to Cu. Cu can reduce Ag+Ag^{+} to Ag.