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Question

Chemistry Question on Group 16 Elements

Given below are two statements :
Statement I: The boiling point of hydrides of Group 16 elements follow the order
H2O > H2Te > H2Se > H2S.
Statement II: On the basis of molecular mass, H2O is expected to have lower boiling point than the other members of the group but due to the presence of extensive H-bonding in H2O, it has higher boiling point.
In the light of the above statements, choose the correct answer from the options given below :

A

Both Statement I and Statement II are true

B

Both Statement I and Statement II are false

C

Statement I is true but Statement II is false

D

Statement I is false but Statement II is true

Answer

Both Statement I and Statement II are true

Explanation

Solution

1. The boiling point order is determined by molecular mass and hydrogen bonding.

2. H2OH_2O has extensive hydrogen bonding, giving it the highest boiling point.

3. Heavier hydrides (H2TeH_2Te, H2SeH_2Se, H2SH_2S) follow boiling point trends based on molecular mass.