Question
Chemistry Question on Group 16 Elements
Given below are two statements :
Statement I: The boiling point of hydrides of Group 16 elements follow the order
H2O > H2Te > H2Se > H2S.
Statement II: On the basis of molecular mass, H2O is expected to have lower boiling point than the other members of the group but due to the presence of extensive H-bonding in H2O, it has higher boiling point.
In the light of the above statements, choose the correct answer from the options given below :
Both Statement I and Statement II are true
Both Statement I and Statement II are false
Statement I is true but Statement II is false
Statement I is false but Statement II is true
Both Statement I and Statement II are true
Solution
1. The boiling point order is determined by molecular mass and hydrogen bonding.
2. H2O has extensive hydrogen bonding, giving it the highest boiling point.
3. Heavier hydrides (H2Te, H2Se, H2S) follow boiling point trends based on molecular mass.