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Question

Chemistry Question on Hybridisation

Given below are two statements: Statement I: PF5\text{PF}_5 and BrF5\text{BrF}_5 both exhibit sp3d\text{sp}^3\text{d} hybridisation.Statement II: Both SF6\text{SF}_6 and [Co(NH3)6]3+[\text{Co}(\text{NH}_3)_6]^{3+} exhibit sp3d2\text{sp}^3\text{d}^2 hybridisation. In the light of the above statements,choose the correct answer from the options given below:

A

Statement I is true but Statement II is false

B

Both Statement I and Statement II are true

C

Both Statement I and Statement II are false

D

Statement I is false but Statement II is true

Answer

Both Statement I and Statement II are false

Explanation

Solution

The hybridisation of the given molecules is as follows:

MoleculeMoleculeHybridisationHybridisation
PF5\text{PF}_5sp3dsp^3d
BrF5\text{BrF}_5sp3d2sp^3d^2
SF6\text{SF}_6sp3d2sp^3d^2
[Co(NH3)6]3+[\text{Co(NH}_3\text{)}_6]^{3+}d2sp3d^2sp^3

Thus, both Statement I and Statement II are false.