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Question

Chemistry Question on subshell electronic configuration

Given below are two statements:
Statement (I) : In the Lanthanoids, the formation of Ce+4 is favoured by its noble gas configuration.
Statement (II) : Ce+4 is a strong oxidant reverting to the common +3 state.
In the light of the above statements, choose the most appropriate answer from the options given below:

A

Both Statement I and Statement II are true

B

Statement I is false but Statement II is true

C

Statement I is true but Statement II is false

D

Both Statement I and Statement II are false

Answer

Both Statement I and Statement II are true

Explanation

Solution

Ce4+\text{Ce}^{4+} has a noble gas electronic configuration, making Statement (I) true. Due to its high reduction potential, the Ce4+/Ce3+\text{Ce}^{4+}/\text{Ce}^{3+} couple acts as a strong oxidizing agent, making Statement (II) true as well.

The correct option is (A) : Both Statement I and Statement II are true