Question
Chemistry Question on Reaction Mechanisms & Synthesis
Given below are two statements:
Statement (I) : SN2 reactions are 'stereospecific', indicating that they result in the formation only one stereo-isomers as the product.
Statement (II) : SN1 reactions generally result in formation of product as racemic mixtures.
In the light of the above statements, choose the correct answer from the options given below :
Statement I is true but Statement II is false
Statement I is false but Statement II is true
Both Statement I and Statement II is true
Both Statement I and Statement II is false
Both Statement I and Statement II is true
Solution
SN2 reactions are stereospecific and proceed via a backside attack, resulting in the inversion of configuration at the chiral center.
SN1 reactions occur via a carbocation intermediate, which is planar. As a result, nucleophiles can attack from either side, leading to a racemic mixture of products.
Thus:
SN2→Inversion (stereospecific),SN1→Racemization.
Both statements are correct.