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Question

Chemistry Question on Organic Chemistry

Given below are two statements :
Statement I: Nitration of benzene involves the following step –
Reaction
Statement II: Use of Lewis base promotes the electrophilic substitution of benzene. In the light of the above statements.
Choose the most appropriate answer from the options given below :

A

Both Statement I and Statement II are incorrect

B

Statement I is correct but Statement II is incorrect

C

Both Statement I and Statement II are correct

D

Statement I is incorrect but Statement II is correct

Answer

Statement I is correct but Statement II is incorrect

Explanation

Solution

In the nitration of benzene, concentrated H2SO4\text{H}_2\text{SO}_4 and HNO3\text{HNO}_3 act as reagents to generate the electrophile NO2+\text{NO}_2^+:
Chemical Reaction

Lewis acids (not bases) promote the formation of electrophiles, facilitating electrophilic substitution. Thus, this statement is incorrect.

Hence, Statement I is correct, and Statement II is incorrect.