Question

Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R).
A ⇒ Spin only magnetic moment of [Fe(CN)6]–3 is 1.73 B.M. and [Fe(H2O)6]+3 is 5.92 B.M.
R ⇒ In both cases Fe have +3 oxidation state
In the light of the above statements, write the detailed answer:

Answer 1

[Fe(CN)6]–3 : Fe+3 : 3d5 with S.F.L
$⇒ n = 1$
Magnetic moment = $1.73$ B.M [Fe(H2O)6]+3 Fe+3 : 3d5 with W.F.L
$⇒ n = 5$
Magnetic moment = $5.92$ B.M

$\text{Both A \& R are correct but R is not the correct explanation }$