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Question

Chemistry Question on Aldehydes, Ketones and Carboxylic Acids

Given below are two statements: One is labelled as Assertion A and the other is labelled as Reason RR
Assertion A :

reduced using Zn - Hg / HCl

can be easily reduced using ZnHg/HClZn - Hg / HCl to

reduce carbonyl group to - CH _2- group
Reason R :**** ZnHg/HCl Zn \cdot Hg / HCl is used to reduce carbonyl group to CH2- CH _2- group.

In the light of the above statements, choose the correct answer from the options given below:

A

A is false but RR is true

B

Both A and RR are true but RR is not the correct explanation of AA

C

A is true but RR is false

D

Both A and R are true and RR is the correct explanation of AA

Answer

A is false but RR is true

Explanation

Solution

The correct answer is (A) : A is false but R is true
clemmenson reduction

The acid sensitive alcohol group reacts with HCl , hence Clemmenson reduction is not suitable for above conversion.