Solveeit Logo

Question

Chemistry Question on Laws of thermodynamics

Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R
Assertion A: In an Ellingham diagram, the oxidation of carbon to carbon monoxide shows a negative slope with respect to temperature
Reason R: CO tends to get decomposed at higher temperature
In the light of the above statements, choose the correct answer from the options given below

A

A is correct but RR is not correct

B

AA is not correct but RR is correct

C

Both AA and RR are correct and RR is the correct explanation of AA

D

Both AA and RR are correct but RR is NOT the correct explanation of AA

Answer

A is correct but RR is not correct

Explanation

Solution

Correct answer is (a): A is correct but R is not correct
2C(s)+O2​(g)→2CO(g)
Δr​S0 is +ve,Δr​G0=Δr​H0−TΔr​S0; thus slope is negative
As temperature increases Δr​G0 becomes more negative thus it has lower tendency to get decomposed.