Question
Chemistry Question on Laws of thermodynamics
Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R
Assertion A: In an Ellingham diagram, the oxidation of carbon to carbon monoxide shows a negative slope with respect to temperature
Reason R: CO tends to get decomposed at higher temperature
In the light of the above statements, choose the correct answer from the options given below
A is correct but R is not correct
A is not correct but R is correct
Both A and R are correct and R is the correct explanation of A
Both A and R are correct but R is NOT the correct explanation of A
A is correct but R is not correct
Solution
Correct answer is (a): A is correct but R is not correct
2C(s)+O2(g)→2CO(g)
ΔrS0 is +ve,ΔrG0=ΔrH0−TΔrS0; thus slope is negative
As temperature increases ΔrG0 becomes more negative thus it has lower tendency to get decomposed.