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Question

Chemistry Question on Some Applications of d- and f-Block Elements

Given below are two statements: One is labelled as Assertion A and the other is labelled as Reason R.

Assertion A: Permanganate titrations are not performed in presence of hydrochloric acid.

Reason R: Chlorine is formed as a consequence of oxidation of hydrochloric acid.

In the light of the above statements, choose the correct answer from the options given below.

A

Both A and R are true and R is the correct explanation of A

B

Both A and R are true but R is NOT the correct explanation of A

C

A is true but R is false

D

A is false but R is true

Answer

Both A and R are true and R is the correct explanation of A

Explanation

Solution

2KMnO4+16HCl2MnCl2+2KCl+8H2O+5Cl22KMnO_4+16HCl→2MnCl_2+2KCl+8H2O+5Cl_2

HClHCl gets oxidised by KMnO4KMnO_4 into Cl2Cl_2