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Question

Chemistry Question on Atomic Models

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).
Assertion (A) : The ionic radii of O2O^{2–} and Mg2+Mg^{2+} are same.
Reason (R) : Both O2O^{2–} and Mg2+Mg^{2+} are isoelectronic species.
In the light of the above statements, choose the correct answer from the options given below.

A

Both (A) and (R) are true and (R) is the correct explanation of (A).

B

Both (A) and (R) are true but (R) is not the correct explanation of (A).

C

(A) is true but (R) is false.

D

(A) is false but (R) is true.

Answer

(A) is false but (R) is true.

Explanation

Solution

Correct order of ionic radii:

O2>Mg+2O^{–2} > Mg^{+2}

This is because among isoelectronic species, the size of anions are greater than the size of cations.

Statement (II) is correct as both O2O^{–2} and Mg+2Mg^{+2} are isoelectronic.

Hence, the correct option is (D): (A) is false but (R) is true.