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Question: Given below are some elements of the modern periodic table: \[_4{\text{Be,}}{{\text{ }}_{26}}{\tex...

Given below are some elements of the modern periodic table:
4Be, 26Fe, 14Si, 19K, 20Ca_4{\text{Be,}}{{\text{ }}_{26}}{\text{Fe,}}{{\text{ }}_{14}}{\text{Si,}}{{\text{ }}_{19}}{\text{K,}}{{\text{ }}_{20}}{\text{Ca}}
(i) Select the element that has one electron in the outermost shell and write its electronic
configuration.
(ii) Select two elements that belong to the same group. Give reason for your answer.
(iii) Select two elements that belong to the same period. Which one of the two has bigger
atomic size?

Explanation

Solution

From the element symbol, determine the atomic number and the number of electrons. Then write the electronic configuration and the valence shell electronic configuration. After that we will be able to identify the valence electrons and the related chemical properties.

Complete Step by step answer: Summarize the element name, atomic number and electronic configuration in the table as shown below:

ElementSymbolElementnameAtomic NumberNumber ofelectronsElectronic configurationValence shellElectronic configuration
4Be_4{\text{Be}}Beryllium441s22s2{\text{1}}{{\text{s}}^2}2{s^2}2s22{s^2}
26Fe_{26}{\text{Fe}}Iron2626[Ar]3d64s2\left[ {{\text{Ar}}} \right]{\text{3}}{{\text{d}}^6}4{s^2}3d64s2{\text{3}}{{\text{d}}^6}4{s^2}
14Si_{14}{\text{Si}}Silicon1414[Ne]3s23p2\left[ {{\text{Ne}}} \right]{\text{3}}{{\text{s}}^2}3{{\text{p}}^2}3s23p2{\text{3}}{{\text{s}}^2}3{{\text{p}}^2}
19K_{19}{\text{K}}Potassium1919[Ar]4s1\left[ {{\text{Ar}}} \right]4{s^1}4s14{s^1}
20Ca_{20}{\text{Ca}}Calcium2020[Ar]4s2\left[ {{\text{Ar}}} \right]4{s^2}4s24{s^2}

(i) The element that has one electron in the outermost shell is potassium having symbol 19K_{19}{\text{K}}
And atomic number 19. It has 19 electrons out of which one electron is present in the outermost shell (the valence shell). Its electronic configuration 1s22s22p63s23p64s1{\text{1}}{{\text{s}}^2}2{s^2}2{p^6}3{s^2}3{p^6}4{s^1} or [Ar]4s1\left[ {{\text{Ar}}} \right]4{s^1}. Its valence shell electronic configuration is 4s14{s^1} .

(ii) The two elements that belong to the same group are beryllium and calcium. They have similar valence shell electronic configuration of ns2n{s^2} .
The element beryllium has symbol 4Be_4{\text{Be}} and atomic number 4. It has 4 electrons out of which, two electrons are present in the outermost shell (the valence shell). Its electronic configuration 1s22s2{\text{1}}{{\text{s}}^2}2{s^2}. Its valence shell electronic configuration is 2s22{s^2} .

The element calcium has symbol 20Ca_{20}{\text{Ca}} and atomic number 20. It has 20 electrons out of which, two electrons are present in the outermost shell (the valence shell). Its electronic configuration [Ar]4s2\left[ {{\text{Ar}}} \right]4{s^2}. Its valence shell electronic configuration is 4s24{s^2} .

(iii) The elements iron, potassium and calcium belong to the same period. They belong to the fourth period. When moving from left to right in the period, there is a gradual decrease in the atomic radius. Due to this, potassium has bigger atomic size than calcium and iron.

Note: In the modern periodic table, elements are arranged in the increasing order of their atomic numbers. The physical and chemical properties of the elements are the periodic functions of the atomic numbers.