Question
Question: Give the IUPAC name of the following compound- Isopropyl alcohol....
Give the IUPAC name of the following compound- Isopropyl alcohol.
Solution
Iso group can be defined as the structural isomer of a straight chain alkane where the second carbon will be attached to a methyl group. When any functional group is attached to the second carbon, the hydrocarbon will be called as a secondary carbon.
Complete step by step solution
Alcohols are the functional group where the hydrocarbon is attached to the −OH group. The hydrocarbons can include alkanes, alkenes, aromatic compounds, etc.
A Primary alcohol will be said to the compound where the alcoholic group is attached to the carbon which is attached to only one carbon. For example, Propan−1−ol that can be represented as
A secondary alcohol will be said to the compound where the alcoholic group is attached to the carbon which is attached to two carbons in the structure. For example, Butan−2−ol that can be represented as
A tertiary alcohol will be said to the compound where the alcoholic group is attached to the carbon which is attached to three carbons in the structure. For example, 2−Methylpropan−2−ol that can be represented as
On oxidation of primary alcohol we get an aldehyde. But on oxidising a secondary alcohol, a ketone is usually formed.
The structure of isopropyl alcohol can be represented as-
The IUPAC naming can be done as-
In the first step, as we can see from the above structure that the compound has three carbon in the longest chain and it does not contain double or triple bond, hence the name of the compound will start from Propan−
In the second step, the suffix used to represent an alcoholic group in a compound will be “ −ol ”.
In the last step the position of alcohol will be noted and that is 2 from the either side.
Hence the IUPAC name of Isopropyl alcohol will be Propan−2−ol .
Note: When we oxidise the alcohols we get an aldehyde or a ketone depending on the type of carbon where the alcoholic group is attached. On oxidation of primary alcohol we get an aldehyde. But on oxidising a secondary alcohol, a ketone is usually formed like on oxidising isopropyl alcohol with PCC we will get acetone.