Question
Question: Give the formula of the following functional groups (A) Aldehyde (B) Ketone...
Give the formula of the following functional groups
(A) Aldehyde
(B) Ketone
Solution
Aldehydes and ketones are organic compounds that have a carbonyl functional group, C = O. These are compounds with general formula, - CHO and , where R and R’ are alkyl groups.
Complete step by step answer:
Aldehydes are compounds where the carbonyl group has one hydrogen atom attached to it along with either a 2nd hydrogen atom or a hydrocarbon group that can be an alkyl group or a group containing a benzene ring.
The smallest aldehyde is formaldehyde.
Whereas in ketones, the carbonyl group has two hydrocarbon groups attached to it. The groups can be either containing benzene rings or alkyl groups. A hydrogen atom is not present attached to the carbonyl group in ketone. The smallest ketone is acetone.
Aldehydes and Ketones also known as methanoyl or formyl group. This is because their carbon atom has two remaining bonds that might be bonded to aryl or alkyl or substituents. The compound is a Ketone, If none of these substituents is hydrogen. The compound is an Aldehyde, If at least one of the substituent is hydrogen.
Aldehydes are more reactive than ketones, this is because in ketones, the two alkyl/aryl groups provide steric hindrance during reactions. But in aldehyde, as the hydrogen atom is relatively small, steric hindrance is not present. Also, the electron donating nature of the two alkyl groups reduce the electrophilicity of carbonyl carbon, whereas this effect is less in aldehydes.
Hence, the answer is a formula of functional group in aldehyde is - CHO and ketone is RC(=O)R′ .
Note: The ketones are more polar than aldehydes.This is due to the presence of two electron-donating R-groups in ketones, this increases the boiling points of ketones and aldehydes.
Aldehydes and ketones have numerous applications due to their chemical properties. Formaldehyde is used in tanning, preparing glues and polymeric products, it is also used as fungicides, germicides and insecticides for plants. It also finds use in and photography drug testing.