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Question

Chemistry Question on Chemical bonding and molecular structure

From the molecular orbital theory, one can show that the bond order in F2F_{2} molecule as

A

2

B

1

C

3

D

4

Answer

1

Explanation

Solution

According to molecular orbital theory,
F2(18)=σ1s2,σ1s2,σ2s2,σ2s2,σ2pz2,π2px2F_{2}(18)=\sigma 1 s^{2}, \overset{*}{\sigma} 1 s^{2}, \sigma 2 s^{2}, \overset{*}{\sigma} 2 s^{2}, \sigma 2 p_{z}^{2}, \pi 2 p_{x}^{2}
π2py2,π2px2π2py2\approx \pi 2 p_{y}^{2}, \overset{*}{\pi} 2 p_{x}^{2} \approx \overset{*}{\pi} 2 p_{y}^{2}
\therefore Bond order in F2=NbNa2=1082=1F_{2}=\frac{N_{b}-N_{a}}{2}=\frac{10-8}{2}=1