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Question: From the following observations predict the type of orbital: Observation 1: x y plane acts as nodal ...

From the following observations predict the type of orbital: Observation 1: x y plane acts as nodal plane Observation 2: The angular function of the orbital intersect the three axis at origin only. Observation 3: R²(r)v/sr curve is obtained for the orbital is

A

5p

B

6d

C

6d2-2

D

6 d

Answer

The question is flawed due to contradictory information. No single correct option can be definitively determined.

Explanation

Solution

The question contains contradictory information.

  1. The radial probability distribution curve shows 5 peaks, implying nl=5n-l=5. None of the options (5p, 6d) satisfy this (nl=4n-l=4 for both).

  2. "x y plane acts as nodal plane" means the orbital wave function is zero at z=0. This is true for pzp_z, dxzd_{xz}, and dyzd_{yz} orbitals. Options (B) 6dxy6d_{xy} and (C) 6dx2y26d_{x^2-y^2} do not have xy as a nodal plane. Option (A) 5pz5p_z would satisfy this condition.

  3. "The angular function of the orbital intersect the three axis at origin only" is ambiguous. If interpreted as axes being nodal lines, it fits dxy,dyz,dxzd_{xy}, d_{yz}, d_{xz}.

Due to these inconsistencies, a definitive answer cannot be determined from the given options and observations.