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Question

Chemistry Question on Stoichiometry and Stoichiometric Calculations

Formation of polyethylene from calcium carbide takes place as follows CaC2+2H2OCa(OH)2+C2H2 CaC _{2}+2 H _{2} O \longrightarrow Ca ( OH )_{2}+ C _{2} H _{2} C2H2+H2C2H4C _{2} H _{2}+ H _{2} \longrightarrow C _{2} H _{4} nC2H4(CH2CH2)n nC _{2} H _{4} \longrightarrow\left(- CH _{2}- CH _{2}-\right) n The amount of polyethylene obtained from 64.1kg64.1\, kg of CaC2CaC _{2} is

A

7 Kg

B

14 Kg

C

21 Kg

D

28 Kg

Answer

28 Kg

Explanation

Solution

The concerned chemical reactions are
(i) CaC264kg+2H2OCa(OH)2+C2H2Ethyne,26kg\underset{64\,kg}{CaC _{2}}+2 H _{2} O \longrightarrow Ca ( OH )_{2}+ \underset{\text{Ethyne}, 26\,kg}{C _{2} H _{2}}
(ii) C2H2+H2C2H4Ethylene,28kgC _{2} H _{2}+ H _{2} \longrightarrow \underset{\text{Ethylene},28\,kg}{C _{2} H _{4}}
(iii) nC2H2n×28kgor28kg[CH2CH2]nn×28kgpolythene or 28kg\underset{n\times 28\,kg \,or\, 28\,kg}{nC _{2} H _{2}} \longrightarrow \underset{n\times 28\,kg\, \text{polythene or }28\,kg}{\left[- CH _{2}- CH _{2}-\right] n}
Thus 64kg64 \,kg of CaC2CaC _{2} gives 26kg26\, kg of acetylene which in turn gives 28kg28\, kg of ethylene whose 28kg28\, kg gives 28kg28\, kg of the polymer, polythene.