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Question

Chemistry Question on Chemical bonding and molecular structure

Formation of \cePCl3\ce{PCl_3} is explained on the basis of what hybridisation of phosphorus atom

A

\ceSP2\ce{SP^2}

B

\ceSP3\ce{SP^3}

C

\ceSP3d\ce{SP^3 d }

D

\ceSP3d2\ce{SP^3 d^2}

Answer

\ceSP3\ce{SP^3}

Explanation

Solution

The type of hybridisation in an atom can be determined By using the formula

H=12[V+YC+A]H=\frac{1}{2}[V+Y-C+A]

Here, V=V= valence shell electrons of the central atom

Y=Y= number of monovalent atom

C=C= total positive charge and

A=A= total negative charge In case of PCl3PCl _{3}
H=12[5+3]=4H=\frac{1}{2}[5+3]=4

Hybridisation of phosphorus atom is sp3s p^{3}.

Pyramidal shape (due to presence of one lone pair of electron.)