Solveeit Logo

Question

Chemistry Question on Thermodynamics

For vaporization of water at 1 atmospheric pressure, the values of ΔH\Delta H and ΔS\Delta S are 40.63kJmol140.63 \, kJ \, mol^{-1} and 108.8JK1mol1108.8 \, JK^{-1} mol^{-1}, respectively. The temperature when Gibbs energy change (ΔG)(\Delta G) for this transformation will be zero, is

A

393.4 K

B

373.4 K

C

293.4 K

D

273.4 K

Answer

373.4 K

Explanation

Solution

ΔG=ΔHTΔSΔG=0{\Delta G = \Delta H - T \Delta S \Delta G =0 }
Given ΔH=TΔS, \Delta H = T \Delta S,
T=40.63×103108.8=373.4KT = \frac{40.63 \times 10^{3}}{108.8 } = 373.4 K