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Question

Chemistry Question on Equilibrium

For the reversible reaction A(s)+B(g)C(g)+D(g)ΔG=350kJA_{(s)}+B_{(g)}\leftrightharpoons C_{(g)} +D_{(g)} \Delta G^\circ=-350kJ which one of the following statements is true?

A

lire reaction is thermodynamically nonfeasible

B

The entropy change is negative

C

Equilibrium constant is greater than one

D

The reaction should be instantaneous

Answer

Equilibrium constant is greater than one

Explanation

Solution

A(s)+B(g)C(g)+D(g),ΔG=350kJA(s)+B(g) \rightleftharpoons C(g)+D(g), \Delta G^{\circ}=-350\, kJ

Relationship between ΔG\Delta G^{\circ} and equilibrium constant is

ΔG=2.303RTlogKp\Delta G^{\circ}=-2.303\, R T \log K_{p}

When Kp>1;ΔGK_{p} >1 ; \Delta G^{\circ} is negative.