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Question

Chemistry Question on Equilibrium

For the reaction N2O4(g)2NO2(g)\text{N}_2\text{O}_4(g) \rightleftharpoons 2\text{NO}_2(g), Kp=0.492atmK_p = 0.492 \, \text{atm} at 300 K. KcK_c for the reaction at the same temperature is _____ ×102\times \, 10^{-2}.
(Given: R=0.082L atm mol1K1R = 0.082 \, \text{L atm mol}^{-1} \text{K}^{-1})

Answer

To convert KpK_p to KcK_c:

Kp=Kc(RT)ΔngK_p = K_c \cdot (RT)^{\Delta n_g}

For the reaction N2O4(g)2NO2(g)\text{N}_2\text{O}_4(g) \leftrightharpoons 2\text{NO}_2(g),

Δng=21=1\Delta n_g = 2 - 1 = 1

Therefore:

Kc=KpRT=0.4920.082×300=2×102K_c = \frac{K_p}{RT} = \frac{0.492}{0.082 \times 300} = 2 \times 10^{-2}

So, the correct answer is: 2×1022 \times 10^{-2}

Explanation

Solution

To convert KpK_p to KcK_c:

Kp=Kc(RT)ΔngK_p = K_c \cdot (RT)^{\Delta n_g}

For the reaction N2O4(g)2NO2(g)\text{N}_2\text{O}_4(g) \leftrightharpoons 2\text{NO}_2(g),

Δng=21=1\Delta n_g = 2 - 1 = 1

Therefore:

Kc=KpRT=0.4920.082×300=2×102K_c = \frac{K_p}{RT} = \frac{0.492}{0.082 \times 300} = 2 \times 10^{-2}

So, the correct answer is: 2×1022 \times 10^{-2}