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Question

Chemistry Question on Equilibrium

For the reaction, SO2(g)+12O2(g)SO3(g)SO_2 ( g) + \frac{1}{2} O_2 \, ( g) \rightleftharpoons SO_3 \, ( g) if KP=KC(RT)xK_P = K_C \, ( RT)^x X where, the symbols have usual meaning, then the value of x is (assuming ideality)

A

-1

B

- 12\frac{1}{2}

C

12\frac{1}{2}

D

1

Answer

- 12\frac{1}{2}

Explanation

Solution

SO2(g)+12O2(g)SO3(g)SO _{2}( g )+\frac{1}{2} O _{2}( g ) \rightleftharpoons SO _{3}( g )
Kp=KC(RT)xK _{ p }= K _{ C }( RT )^{ x }
x=Δng=x =\Delta n _{ g }= no. of gaseous moles in product

- no. of gaseous moles in reactant

=1(1+12)=132=12=1-\left(1+\frac{1}{2}\right)=1-\frac{3}{2}=\frac{-1}{2}