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Question

Question: For the reaction of one mole of zinc dust with one mole of sulphuric acid in a bomb calorimeter, \(\...

For the reaction of one mole of zinc dust with one mole of sulphuric acid in a bomb calorimeter, Δ\DeltaU and w correspond to

A

ΔU<0,w=0\Delta U < 0,w = 0

B

ΔU=0,w<0\Delta U = 0,w < 0

C

ΔU>0,w=0\Delta U > 0,w = 0

D

ΔU<0,w>0\Delta U < 0,w > 0

Answer

ΔU<0,w=0\Delta U < 0,w = 0

Explanation

Solution

Bomb calorimeter is commonly used to find the heat of combustion of organic substances which consists of a sealed combustion chamber, called a bomb. If a process is run in a sealed container then no expansion or compression is allowed, so w = 0 and Δ\DeltaU = q.

Δ\DeltaU < 0, w = 0