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Question: For the reaction, N<sub>2</sub> (g) + 3H<sub>2</sub> (g) <img src="https://cdn.pureessence.tech/canv...

For the reaction, N2 (g) + 3H2 (g) 2NH3 (g) DH = –93.6 kJ/mol

For reaction, 12\frac { 1 } { 2 }N2 (g) + 32\frac { 3 } { 2 }H2 (g)NH3 (g) DH¢

Which of the following is/are correct?

A

At any given temperature Keq

B

On increasing temperature Keq increases at a greater proportion than...

C

Both (1)&(2) are correct

D

Neither (1) nor (2) is correct

Answer

At any given temperature Keq

Explanation

Solution

DH ¢ = 93.62\frac { - 93.6 } { 2 }kJ/mol

\ ln=×ΔTT1 T2\frac { \Delta \mathrm { T } } { \mathrm { T } _ { 1 } \mathrm {~T} _ { 2 } } and ln(Keq)T2( Keq)T1\frac { \left( \mathrm { K } _ { \mathrm { eq } } ^ { \prime } \right) _ { \mathrm { T } _ { 2 } } } { \left( \mathrm {~K} _ { \mathrm { eq } } ^ { \prime } \right) _ { \mathrm { T } _ { 1 } } }=ΔHR\frac { \Delta \mathrm { H } ^ { \prime } } { \mathrm { R } }×ΔTT1 T2\frac { \Delta \mathrm { T } } { \mathrm { T } _ { 1 } \mathrm {~T} _ { 2 } }

On increasing temperature Keq & both decreases.