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Question: For the reaction \(N{H_3}\, + \,{O_{2\,}} \to \,NO + \,{H_2}O\) how many grams of \({O_{2\,}}\) are ...

For the reaction NH3+O2NO+H2ON{H_3}\, + \,{O_{2\,}} \to \,NO + \,{H_2}O how many grams of O2{O_{2\,}} are needed to completely react with 85.15gofNH385.15g\,of\,N{H_3} ?

Explanation

Solution

Firstly balance the chemical reaction given above, then see how many moles of ammonia reacts with oxygen. In these types of reactions, generally we have 1:11:1 between the two reactants and thus after applying the mole concept the same amount of one reactant reacts with the other one. Balance and see the molar ratio here. Mole ratio may be other than just 1:11:1 .

Complete step by step answer:
Firstly we have to balance the given chemical reaction. To balance it, we multiply the oxygen on the left hand side by 55 it will make a total of 10oxygen10\,oxygen on the left hand side 5O25{O_2} . Then we will balance oxygen atoms of the right hand side by multiplying H2O{H_2}O by 66 . This will make oxygen somewhere nearer to oxygen of left hand side i.e. 5O25{O_2} but now we have to balance other atoms, we get 12hydrogen12\,hydrogen on right hand side, balance hydrogen on left hand side by multiplying ammonia with 44 this will balance hydrogen, at last balance remaining atoms. Here only nitrogen is left to balance which on multiplying NONO by 44 balances the whole equation.
We get, 4NH3+5O24NO+6H2O4N{H_3}\, + \,5{O_{2\,}} \to \,4NO + \,6{H_2}O
Now let’s proceed to the main part of our question that is to find the amount of O2{O_{2\,}} to react with 85.15gofNH385.15g\,of\,N{H_3} .
Here the molar ratio of 4:54:5 is in between NH3N{H_3}\, and O2{O_{2\,}} it means 4moleofNH34\,mole\,of\,N{H_3} are needed to react with 5moleofH2O5\,mole\,of\,{H_2}O . We have 85.15gofNH385.15g\,of\,N{H_3} thus it is equivalent to 5mole5\,mole thus we need 54moleofoxygen\dfrac{5}{4}mole\,of\,oxygen according to the equation stoichiometry given below.
NH3+54O2NO+64H2ON{H_3}\, + \,\dfrac{5}{4}{O_{2\,}} \to \,NO + \,\dfrac{6}{4}{H_2}O
Calculating the exact moles of ammonia present here by the formula of number of moles, number of moles are the ratio of given mass to molar mass.
molesofNH3=givenmassofNH3molarmassofNH3moles\,of\,N{H_3} = \dfrac{{given\,mass\,of\,N{H_3}}}{{molar\,mass\,of\,N{H_3}\,}}
molesofNH3=85.15g17.03gmol1moles\,of\,N{H_3} = \dfrac{{85.15g}}{{17.03\,g\,mo{l^{ - 1}}\,}}
molesofNH3=5molesmoles\,of\,N{H_3} = 5\,moles
So, now calculating amount of oxygen by multiplying 54×5moles×molarmassofoxygen\dfrac{5}{4} \times \,5\,moles\, \times molar\,mass\,of\,oxygen
Molar mass of oxygen is 3232 , how it will be this for a single oxygen it will be 1616 and for O2{O_{2\,}} it will 3232
54×5×32g\dfrac{5}{4} \times \,5\, \times \,32\,g
200g200\,g

We get 200g200g of oxygen needed for the completion of reaction.

Note: Balance chemical equation first and check for it whether it is balanced or not. We need to see the molar ratio between the reactants which gives us an idea about how much part we need to take for reacting oxygen with ammonia. Here we multiply molar mass of oxygen with 54\dfrac{5}{4} according to the stoichiometry and by 55\, due to moles of ammonia.