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Question

Chemistry Question on Enthalpy change

For the reaction CO(g)+12O2(g)CO2(g)CO ( g )+\frac{1}{2} O _{2}( g ) \rightarrow CO _{2}( g ) Which one of the statement is correct at constant TT and PP ?

A

ΔH=ΔE\Delta H =\Delta E

B

$\Delta H

C

ΔH>ΔE\Delta H >\Delta E

D

ΔH\Delta H is independent of physical state of the reactants

Answer

$\Delta H

Explanation

Solution

Δn=12;ΔH=ΔE12RT;\Delta n=-\frac{1}{2} ; \Delta H=\Delta E-\frac{1}{2} R T ;
ΔE>ΔH\Rightarrow \Delta E>\Delta H