Question
Chemistry Question on Organic Chemistry- Some Basic Principles and Techniques
For the reaction: C3H8(g)+5O2(g)→3CO2(g)+4H2O(l) at constant temperature, ∆H–∆E is:
A
RT
B
-3RT
C
3RT
D
-RT
Answer
-3RT
Explanation
Solution
Mathematically, it can be represented as:
∆H - ∆E = ∆nRT
In this reaction:
The number of moles of gas molecules on the left side (reactants) is 1 (C3H8) + 5 (O2) = 6 moles.
The number of moles of gas molecules on the right side (products) is 3 (CO2).
So, ∆n = (moles of products) - (moles of reactants) = 3 - 6 =-3 moles.
Now,
∆H - ∆E = ∆nRT = (-3)RT = - 3RT
So, the correct answer is (B): -3RT