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Question

Chemistry Question on Organic Chemistry- Some Basic Principles and Techniques

For the reaction: C3H8(g)+5O2(g)3CO2(g)+4H2O(l)C_3H_8(g)+5O_2(g)→3CO_2(g)+4H_2O(l) at constant temperature, ∆H–∆E is:

A

RT

B

-3RT

C

3RT

D

-RT

Answer

-3RT

Explanation

Solution

Mathematically, it can be represented as:
∆H - ∆E = ∆nRT
In this reaction:
The number of moles of gas molecules on the left side (reactants) is 1 (C3H8) + 5 (O2) = 6 moles.
The number of moles of gas molecules on the right side (products) is 3 (CO2).
So, ∆n = (moles of products) - (moles of reactants) = 3 - 6 =-3 moles.
Now,
∆H - ∆E = ∆nRT = (-3)RT = - 3RT

So, the correct answer is (B): -3RT