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Question

Chemistry Question on Thermodynamics

For the reaction at 298K298 \, \text{K}, 2A+BC2\text{A} + \text{B} \rightarrow \text{C}. ΔH=400kJ mol1\Delta H = 400 \, \text{kJ mol}^{-1} and ΔS=0.2kJ mol1K1\Delta S = 0.2 \, \text{kJ mol}^{-1} \, \text{K}^{-1}. The reaction will become spontaneous above ____ K\text{K}.

Answer

For spontaneity, we use the Gibbs free energy equation where ΔG=0\Delta G = 0 at the threshold temperature for spontaneity:

T=ΔHΔS=4000.2=2000KT = \frac{\Delta H}{\Delta S} = \frac{400}{0.2} = 2000 \, \text{K}